Self-Assembly of a Library of Polyborate Chiral Anions for Asymmetric Catalytic Quinoline Reduction.
نویسندگان
چکیده
The 'template' polyborate BOROX catalysts are shown to mediate the asymmetric transfer hydrogenation of 2-quinolines. The rapid and simple generation of a large family of BOROX catalysts with significantly altered asymmetric pockets is described. A transition state model that explains the enantioselectivity is proposed.
منابع مشابه
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عنوان ژورنال:
- Tetrahedron letters
دوره 56 23 شماره
صفحات -
تاریخ انتشار 2015